Non-precious-metal catalysts are increasingly employed for commercial API synthesis. Sebastian Kaulitzki/shutterstock.com Cross-coupling reactions enable the synthesis of complex building blocks and ...
Alternatives to expensive palladium catalysts are gaining acceptance for commercial API synthesis. Cross-coupling reactions enable the synthesis of complex building blocks and intermediates with ...
Chemists have taken one of the most widely used reactions in organic synthesis—the Suzuki-Miyaura cross-coupling reaction—and made it even more versatile by melding it with an award-winning green ...
Recently, photoredox catalysis has emerged as an appealing coupling partner for transition metal catalysis, termed metallaphotocatalysis, to develop new synthetic methodologies as well as improve the ...
The industrially important coupling of aromatic compounds has generally required differential prefunctionalization of the arene coupling partners with a halide and an electropositive group. Here we ...
Negishi cross-coupling reactions have been widely used to form C-C bonds since the 1970s and are often perceived as the result of two metals (i.e zinc and palladium/nickel) working in synergy. But ...
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Proceedings of the National Academy of Sciences of the United States of America, Vol. 111, No. 23 (June 10, 2014), pp. 8368-8373 (6 pages) Despite recent advances of asymmetric synthesis, the ...
Researchers at The Scripps Research Institute (TSRI) have designed a new molecule-building method that uses sulfones as partners for cross-coupling reactions, or the joining of two distinct chemical ...
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